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date: 20 August 2019

Abstract and Keywords

This article discusses nanocatalysis and especially the interrelation between the structure, composition and properties of catalysts. It begins with a review of techniques that have been developed and employed for surface characterization, which can be divided intothree main areas: spectroscopy, diffraction, and microscopy. After describing the nanocharacterization tools, the article considers the theoretical underpinnings of catalysts and catalytic processes. It also examines how detailed atomic-scale insight into elementary surface processes relevant to catalysis can be obtained mainly by means of high-resolution scanning tunnelling microscope studies on single-crystal surfaces. More specifically, it explores the surface structure, adsorption, dissociation and diffusion, and surface chemical reactions of catalysts. The article also looks at the design of new catalysts from first principles and concludes with an assessment of nanocatalysts and transmission electron microscope studies of nanoclusters on high surface area supports.

Keywords: nanocatalysis, surface characterization, nanocharacterization, scanning tunnelling microscope, single-crystal surfaces, surface chemical reactions, first principles, nanocatalysts, transmission electron microscope, nanoclusters

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